By Ian S. Longmuir
Advances in Polarography, quantity 2 covers the lawsuits of the second one overseas Congress held at Cambridge in 1959 in honor of the seventieth birthday of Professor Heyrovsky.
This quantity consists of 35 chapters and starts off with in depth discussions at the theoretical and basic elements, in addition to pertinent equations in polarography. substantial chapters are dedicated to the chemical and metallurgical purposes of the method, with emphasis at the hint selection of sure compounds. the remainder chapters discover different program of particular polarographic strategy, comparable to nicotinic acid, iso-benzpyrylium salts, and steel complicated research.
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Extra resources for Advances in Polarography. Proceedings of the Second International Congress Held at Cambridge 1959
Kouteckyt 1 ) has pointed out t h a t the success of von Stackelberg's method is fortuitous. This may be so, but it gives the correct result in the case mentioned, and the nearly correct result when applied to the expanding spherical electrode. This was shown by Kambara, Suzuki and Tachi*5) and by K a m b a r a and Tachi^6- 7> (also see ref. 8). These authors replaced equation (1) by oo A= I (C -C)r*dr C'R* J n (4) where R is the radius of the electrode, and r is the distance from its centre. Equation (4) is not perfectly exact either and the further treatment given by all the Japanese authors referred to is still approximate, but their results approach equation (I, 1) quite closely.
Chem. Comm. 12, 594, 1947. 8. GORBUNOVA K. , and ZHUKOVA A. J . Zh. Fis. Khim. 22, 1097, 1948. 9. FISCHER H . Z. Metallic. 39, 204, 1948. 10. LOSHKAREV M. , and K R J U K O V A A. A. Zh. Fis. 11. 12. 13. 14. 15. Khim. 22, 805, 815, 1948; 23, 209, 221, 1949. VAGRAMJAN A. T. Metal-Deposition, Academy of Science USSR Press, 1950. PLESKOV V. , and MILLER N. B. Proceedings of the Third Electrochem. Conference, 1950, pp. 165-170, Moscow, 1953. ERSHLER B . , and ROSENTAL K. J . Proceedings of the Third Electrochem.
Univ. No. 67, 1954. 11. , a n d SCHINDLER R. Z. Elektrochem. Kyoto 60, 1138, 1956. DISCUSSION P . Z U M A N : A n e x a m p l e of t h e possibility of a p p l i c a t i o n of t h e given t r e a t m e n t for irreversible processes would b e some p r o t o n - t r a n s f e r reactions o n t h e p r o d u c t of one-electron r e d u c t i o n . A n e x a m p l e of such a r e a c t i o n is p r o b a b l y t h e reduc t i o n of p h t h a l i m i d e s , s t u d i e d b y Tirouflet a n d R y v o l o v a .