By Bertil Aronsson, Torsten Lundström, Ingvar Engström (auth.), Fred W. Vahldiek, Stanley A. Mersol (eds.)
Read or Download Anisotropy in Single-Crystal Refractory Compounds: Proceedings of an International Symposium on Anisotropy in Single-Crystal Refractory Compounds, held on June 13–15, 1967, in Dayton Ohio. Sponsored by the Ceramics and Branch of the air Force Materials La PDF
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Extra info for Anisotropy in Single-Crystal Refractory Compounds: Proceedings of an International Symposium on Anisotropy in Single-Crystal Refractory Compounds, held on June 13–15, 1967, in Dayton Ohio. Sponsored by the Ceramics and Branch of the air Force Materials La
1, as an example, are given the integral widths of Debye-Scherrer lines of an ammonia catalyst which was promoted with 3 weight % of AI Z0 3 . Z In the 6 b - n -plot in accordance with (Z3) straight lines arise for the single n families of net planes. From the slope of these lines one obtains the respective g-values, which are given in Table 1. From the intersection of these lines with the ordinates n = respective diameters 15 N a 0, one obtains the 44 CRYSTAL STRUCTURE AND CHEMISTRY Table I Paracrystals in AI-promoted ammonia catalysts Annealing - Lattice planes a 15 (R) (R) g (%) a h h h h h 0 0 h 0 1.
5. MozC crystal (C-9), transverse surface, 606 x. ' . 8 Fig. 6. MozC crystal (C-9), longitudinal surface, 606 x. _~. •• V ~_ _ U ... t . ,.. ' ,,~ ... ,.. ~ 'W: ~_ ~L • 't ~~.... _ : .. \4 3 w/o / B-2 0 Fig. 7. Ta distribution, single crystal MozC, C-8 (CS), edge. _V V. ...... • ;; 60 __ 7Q~ _ _ _ _ 50 _. __ . < :...... - _ _ - _ . I ,! __ 2 _____ ~. l _ _ _ _ _ _ . -/ hU <&r
An 100 netplane of a-Fe. The FeAl z0 4 molecule is too thick. CRYSTAL STRUCTURE AND CHEMlSTRY 48 Table Z Paracrystals in Mn x ~ x Fe 3 -x 04 spinels lattice plane g (%) 1. 01 >ZOOO 1. 19 the promoted catalyst is the same as that of the unpromoted one. The shape of this molecule, however, is not the same as that of the seven Fe-atoms, since the ions too small ones. ° -ions have too large diameters, the Fe ++ - and Al+t+_ This kind of filling in bricks (FeAI Z0 4 ) into a lattice is called "endotaxy".