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By Chi-Ming Chan, Lin Li (auth.), Hans-Henning Kausch (eds.)

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G. cooling down of the nucleated molten PP sample to 100 ◦ C only in order to avoid a β/α - recrystallization during the second heat [70, 109, 110]), Chen et al. 5 J g–1 [78]. A supplementary way to control the efficiency of a β-nucleation is to measure the crystallization temperature, Tc , during the cooling stage. The higher the difference in Tc between the non-nucleated and the corresponding β-nucleated grade is, the more developed is the βphase. However, Tc is dependent on the cooling rate: the lower the cooling rate is, the higher is Tc .

Li 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. Keith HD, Padden Jr FJ (1959) J Polym Sci 39:101 Keller A, Sawada S (1964) Makromol Chem 74:190 Bassett DC, Hodge AM, Olley RH (1981) Proc R Soc A377:25 Bassett DC, Vaughan AS (1985) Polymer 26:717 Olley RH, Bassett DC (1989) Polymer 30:399 Bassett DC (1994) Phil Trans R Soc A 348:29 Li JX, Ness JN, Cheung WL (1996) J Appl Polym Sci 59:1733 Li JX, Cheung WL (1999) J Appl Polym Sci 72:1529 Phillips PJ, Andrews EH (1972) Polym Letters 10:321 Phillips PJ, Edwards BC (1975) J Polym Sci: Polym Phys 13:1819 Edwards BC, Phillips PJ (1975) J Polym Sci: Polym Phys 13:2117 Phillips PJ, Edwards BC (1976) Polym Lett 14:449 Phillips PJ, Sorenson D (1979) J Polym Sci: Polym Phys 17:521 Edwards BC, Phillips PJ, Sorenson D (1980) J Polym Sci: Polym Phys 18:1737 Phillips PJ, Sorenson D (1981) J Polym Sci: Polym Lett 19:585 Rensch GJ, Phillips PJ, Vatansever N (1986) J Polym Sci, Polym Phys 24:1943 Daxaben P, Bassett DC (1994) Phil Trans R Soc Lond A445:577 Bassett DC, Olley RH, Al Raheil IAM (1988) Polymer 29:1539 Bassett DC, Hodge AM (1981) Proc R Soc Lond A 377:25 Padden FJ, Keith HD (1959) J Appl Phys 30:1479 Bassett DC, Olley RH(1984) Polymer 25:935 Keith, HD, Padden FJ (1963) J Appl Phys 34:2409 Binning G, Quate CF, Gerber Ch (1986) Phys Rev Lett 66:930 Rugar D, Hansma P (1990) Physics Today 43:23 Miles JM (1997) Science 277:1845 Magonov SN (1993) Applied Spectroscopy Reviews 28:1 Sheiko SS (2000) Adv Polym Sci 151:61 Magonov SN, Reneker DH (1997) Ann Rev Mat Sci 27:175 Munz M, Capella B, Sturm H, Geuss M (2003) Adv Polym Sci 164:87 Magonov SN, Elings V, Whangbo MH (1997) Surf Sci 375:L385 Bar G, Thomann Y, Brandsch R, Cantow HJ, Whangbo MH (1997) Langmuir 13:3807 Bar G, Delineau L, Brandsch R, Bruch M, Whangbo MH (1997) Appl Phys Lett 75:4198 Bar G, Brandsch R, Whangbo MH (1999) Surf Sci 436:L715 Magonov SN, Godovsky YK (1999) American Laboratory 31:52 Höper R, Gesang T, Possart W, Hennemann OD, Boseck S (1995) Ultramicroscopy 60:17 Magonov SN, Cleveland J, Elings V, Denley D, Whangbo MH (1997) Surf Sci 389:201 Leclère Ph, Lazzaroni R, Brédas JL, Yu JM, Dubois Ph, Jérôme R (1996) Langmuir 12:4317 Patil R, Kim SJ, Smith E, Reneker DH, Weisenhorn AL (1990) Polym Comm 31:455 Snetivy D, Vancso GJ (1992) Polymer 33:432 Pearce R, Vancso GJ (1998) Polymer 39:1237 Pearce R, Vancso GJ (1998) J Polym Sci: Polym Phys 36:2643 Haeringen DTV, Varga J, Ehrenstein GW, Vancso GJ (2000) J Polym Sci: Polym Phys 38:672 Harbon HR, Pritchard RG, Cope BC, Goddard DT (1996) J Polym Sci: Polym Phys 34:173 Crämer K, Wawkuschewski A, Domb A, Cantow HJ, Magonov SN (1995) Polym Bull 35:457 Motomatsu M, Nie HY, Mizutani W, Tokumoto H (1996) Polymer 37:183 43.

Main Differences between the α- and β-Modifications Quantification of the Amount of β-Modification . . Assessment of Mechanical Performance . . . . . . of PP . . . . . . . . . . . . . . . . . . . . 5 Toughness in β-Polypropylene . . . . . Influence of Intrinsic Characteristics . . . Influence of Molecular Weight . . . . . Influence of Polydispersity . . . . . . Influence of a Matrix with Low Ethylene Content Influence of Extrinsic Parameters . . . . Influence of the Content of Nucleating Agent .

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